结晶等（结晶构造、材料样品）

结晶等（结晶构造、材料样品）

Anisotropy keyword”anisotropy”

"Anisotropy" means that physical properties of a crystalline substance are different depending on its crystal orientations. Related term isotropy

glide plane keyword “ glide plane ”

A symmetry element of the crystallographic space group. When a crystal is mirrored with respect to a certain crystal plane (mirror plane) and successively translated parallel to this mirror plane by a length of 1/2 or 1/4 of the crystal unit-cell, the translated crystal can be equivalent to the original crystal. In this case, this plane is called "glide plane." The glide planes are denoted by g, instead of m in the case of mirror planes. Related term crystallographic space group screw axis

inclusion keyword “ inclusion ”

Inclusions are impurity particles captured in a solid.

rotation axis keyword “ rotation axis ”

A symmetry element of the crystallographic point group. When the whole crystal (constituent atoms) is rotated by a certain angle (180°, 120°, 90° or 60°) with respect to a line, the rotated crystal can be equivalent to the crystal before rotation. In this case, this line is called "rotation axis." Corresponding to the respective rotation angles, there exist 2-fold, 3-fold, 4-fold and 6-fold rotation axes. Related term crystallographic point group rotary-inversion axis mirror plane inversion center

rotary-inversion axis keyword “ rotation-inversion axis ”

A symmetry element of the crystallographic point group. When the whole crystal (constituent atoms) is rotated by an angle of 90° with respect to a line, and successively an inversion is operated for the rotated crystal, the resultant crystal can be equivalent to the crystal before the operations. In this case, the combination of the two symmetries is called "rotary-inversion axis." Only the 4-fold rotary-inversion axis is a symmetry of the crystallographic point group. Related term crystallographic point group rotation axis mirror plane inversion center

Interface keyword " interface ”

An "interface" is a boundary surface between two different phases. In the case of crystalline phase, the interface often takes a specific crystalline plane. In materials science, it is important to analyze grain boundaries in metals, and interfaces (boundary surfaces) on multiple layers in semiconductors and ceramics. Related term boundary

Graphical User Interface

"GUI" is a user interface that provides intuitive operations using a computer graphics and a pointing device. Since GUI offers user-friendly operation and high visualization, it is widely used as a major interface for commercial OS. In the TEM, GUI is used to facilitate instrument operation and display of image-data. It is, however, noted that GUI is not always effective because different operations cannot be carried out simultaneously. 7. chemical order/disorder keyword “ chemical order/disorder ” An order about the arrangement of constituent elements in a compound or an alloy. For example, in the case of a compound containing two atoms A and B, a "chemical order" implies that each atom is alternately arranged in an ordered fashion. When each atom is arranged in a random fashion, this state is called a "chemical disorder." The chemical disorder takes place when the chemical properties of the constituent atoms are similar to each other. Compounds or alloys can take a chemical disorder state at high temperature and undergo a chemical order state at low temperature. 8. ordered and disordered structure keyword “ ordered and disordered” For example, in the high-temperature phase of Cu3Au, Cu and Au randomly occupy the lattice points of the face-centered structure. In the low-temperature phase, Au occupies the position of origin and Cu occupies the three face-centered positions. In this manner, the "ordered and disordered structure" means that when the external condition (temperature) changes, the structure of a substance changes where the constituent atoms are arranged orderly or randomly. The order-disorder transformation occurs in not only alloys but also inorganic compounds. If an ordered structure is formed, diffraction spots specific to the structure appear. Related term long-range order parameter short-range order parameter 9-1. boundary keyword “ boundary ” In the case of crystal, a "boundary" separates crystals with different orientations or phases, or it separates crystals with different compositions or structures. Boundaries include stacking fault, twin boundary, inversion domain boundary, anti-phase domain boundary, grain boundary, and multi-layer boundary. Related term stacking fault twins inversion domain boundary grain boundary 9-2. boundary condition The boundary condition is the condition which should be satisfied by the solution function of the differential equation of a scattering problem at the boundary of a crystal. The boundary conditions in the case of the Bethe' s method for the amplitudes of transmitted and diffracted waves are as follows: 1) The amplitudes of the incident electron wave and those inside the crystal are the same at the entrance surface. 2) The tangential components of those electron waves are the same at the entrance surface. Related term Bethe's method 9-3. grain boundary "Grain boundary" separates respective crystalline particles with different orientations in a polycrystalline solid. Grain boundaries are also called crystalline grain boundaries. High-resolution HAADF-STEM image of polycrystalline silicon taken at an accelerating voltage of 300 kV. The boundary indicated by red allows is a grain boundary of crystalline silicon. The image reveals that the dumbbells of silicon atoms change their orientations across the boundary. This grain boundary is expressed by Σ3, [110]/{111}.

Related term boundary 9-4. inversion domain boundary "Inversion domain boundary" separates two adjacent crystals which coincide with each other by an inversion operation. Related term boundary 9-5.anti-phase boundary "Anti-phase boundary" separates two adjacent crystals which have the same crystallographic orientation but have a 180°phase shift (a shift of half period) each other. Anti-phase boundaries frequently appear in the ordered phase of a binary alloy. 10. mirror plane keyword “ mirror plane ” A symmetry element of the crystallographic point group. When the whole crystal (constituent atoms) is mirrored with respect to a certain plane, the mirrored crystal can be equivalent to the crystal before the mirror operation. In this case, this plane is called "mirror plane." Related term crystallographic point group rotation axis glide plane inversion center 11-1. ferromagnetic material keyword “ ferromagnetic material ” A material that consists of atoms having magnetic moments, which align parallel to each other, thus exhibits strong spontaneous magnetic polarizations without any external magnetic field. In a magnetic domain, all the magnetic moments take the same direction. When an external magnetic field is applied to a ferromagnetic material, strong magnetic moments appear in the direction of the magnetic field, and residual magnetic moments exist even after the magnetic field is removed, thus exhibiting a hysteresis loop of the magnetic moment against the magnetic field. Certain materials show ferromagnetism below a phase transformation temperature, called the Curie temperature Tc, and are paramagnetic (disordering of the moments) above the temperature. Related term paramagnetic material diamagnetic material antiferromagnetic material magnetic domain 11-2.antiferromagnetic material An "antiferromagnetic material" consists of atoms having magnetic moments but the neighbouring magnetic moments are aligned anti-parallel to each other, thus the net magnetic moment of the material is 0 (zero). The material is magnetized in the direction of a magnetic field like a paramagnetic material when placed in a weak magnetic field. When the magnetic field is increased, it is strongly magnetized in the direction of the magnetic field like a ferromagnetic material. It exhibits a double-hysteresis loop against changes of the magnetic field. Related term ferromagnetic material paramagnetic material diamagnetic material 12-1.ferroelectric material keyword “ ferroelectric material ” A material that has spontaneous electric polarizations, which can be reversed by the application of an external electric field. In a ferroelectric domain, all the polarizations take the same direction. When an external electric field is applied to a ferroelectric material, strong polarizations appear in the direction of the electric field, and residual electric polarizations exist even after the electric field is removed, thus exhibiting a hysteresis loop of polarization against the external field. Certain materials show ferroelectricity below a phase transformation temperature, called the Curie temperature Tc, and are paraelectric above this temperature. Related term paraelectric material ferroelectric domain antiferroelectric material 12-2. antiferroelectric material An "antiferroelectric material" indicates such a crystal that consists of two sublattices which have anti-parallel dielectric polarizations each other, thus the net polarization of the crystal being 0 (zero). The material is polarized in the direction of an electric field like a paraelectric material when placed in a weak electric field. When the electric field is increased, strong electric polarization is generated in the direction of the electric field like a ferroelectric material. It exhibits a double-hysteresis loop against changes of the electric field. Related term ferromagnetic material paraelectric material 13. chirality keyword “ chirality ” As in the case of the human left-and-right hands, "chirality" means that two certain structures having mirror-image relation to each other cannot coincide through rotation operations. These structures are possible for crystals belonging to the point groups which do not have mirror symmetry and centro-symmetry. 14. intermetallic compound keyword “ intermetallic compound ” A compound that consists of two or more metallic elements. 15. crystallographic space group keyword “ crystallographic space group” Since the unit cells are arranged repeatedly in a crystal, symmetry operations by which a point in a crystal is transformed to an equivalent point of a neighboring unit cell are allowed as symmetry operations leaving the crystal unchanged. These symmetry elements are screw axes and glide planes. "Crystallographic space groups" are constructed by the combinations of the screw axes and the glide planes with the symmetry elements of the crystallographic point groups. There exist 230 space groups. Related term screw axis glide plane crystallographic point group convergent-beam electron diffraction CBED forbidden reflection extinction rule 16. crystal orientation keyword “ crystal orientation ” "Crystal orientation" is defined by the plane (Miller) indices of the lattice plane of a crystal. In observation of an electron microscope image using a TEM, the particular crystal orientation (usually, orientation expressed by the low-order indices) is aligned to the direction of the incident electron beam. The use of a Kikuchi pattern enables us to easily align the crystal orientation with high accuracy. Related term Kikuchi pattern 17-1. crystal structure keyword “ crystal structure ” "Crystal" is an object in which a unit composed of atoms and molecules is periodically arranged. The unit is called a unit cell. If we know the atomic arrangement in the unit cell, we obtain the entire knowledge of the crystal. The arrangement of atoms and molecules in the unit cell is called "crystal structure." In TEM, convergent-beam electron diffraction (CBED) is used for the detailed analysis of the crystal structure. Related term unit cell lattice parameter (constant) crystal structure analysis convergent-beam electron diffraction CBED 17-2. crystal structure analysis For crystal structure analysis, the electron microscope (TEM) image is not used, but the electron diffraction is used because the spatial resolution of the TEM is around 0.1 nm, but the electron diffraction pattern achieves a spatial resolution of 0.001 nm. In structure analysis, there are two methods; one is to use kinematical diffraction, the other is to use dynamical diffraction. The former is applied when a crystalline specimen is thin and consists of light elements and the dynamical diffraction effect can be neglected. Actually, this method is used for protein crystal analysis. The intensities of each reflection are measured from a diffraction pattern. The phases of the reflections are obtained from the real and imaginary parts of the scattering factors which are obtained by Fourier transform of the corresponding TEM image. Then, the structure is obtained by Fourier synthesis of the intensities and phases. The latter method, which uses convergent-beam electron diffraction (CBED), is applied to structure analysis of nano-scale crystals in the field of materials science. The CBED method has more advantage to study the secondary structure of solid materials, or local structures due to lattice defects and lattice strain than to study the primary structure of crystals. A disk diffraction pattern is acquired by illumination of an electron beam with an incidence angle of several 10 mrad on a small specimen area of a diameter of 10 nm or less. The acquired disk diffraction pattern (CBED pattern) exhibits a two-dimensional rocking curve (intensity distribution) corresponding to the spread of the incidence beam angle. (The CBED pattern appears to be complex due to the dynamical diffraction effect, thus the pattern is greatly different from the Laue function or the rocking curve which is expected from kinematical diffraction.) The crystal structure is solved by the fitting between the simulated CBED pattern obtained by the full dynamical calculation and the experimentally-acquired CBED pattern. Since the phases of the diffracted waves are reflected in the diffraction intensities due to multiple diffraction effects, separate determination of the phases of the diffracted waves is not necessary, which is needed in the case of kinematical diffraction. In addition, an energy filter is effectively used to remove inelastic scattering. The third method is the pre-session method. In this method, to avoid the strong dynamical diffraction effect using illumination of a cone-shaped incident beam on a crystalline specimen with a tilt angle of several degrees from a zone axis, the intensities produced by the cone illumination are added for each reflection. The crystal structure is solved by applying the kinematical theory using the obtained intensities, where the direct method for X-ray diffraction is used to estimate the phases of the diffracted waves. Related term crystal structure electron diffraction kinematical diffraction dynamical diffraction convergent-beam electron diffraction CBED rocking curve Laue function energy filter 17-3. crystal structure factor The crystal structure factor gives the amplitude and phase of a diffracted wave from a crystal. The factor is determined by the atom species and their positions in a unit cell. Related term atom form factor 17-4. crystal structure image HREM, which allows wave interference between transmitted and diffracted waves to be caused, enables us to obtain an image exhibiting the crystal structure of a thin crystalline specimen (thickness <10 nm). This image is obtained at the defocus condition, which is determined by the spherical aberration of the objective lens and the accelerating voltage of the incident beam (Scherzer focus). The image is taken by setting the electron beam parallel to a low-order zone axis and by passing a transmitted beam and many diffracted beams through the objective aperture. When the image is not taken at Scherzer focus, it is called "lattice image," which does not always correspond to the crystal structure. Three important factors to take an image corresponding to the crystal structure are: (1) Preparation of a sufficiently thin crystalline specimen, (2) High-accuracy adjustment of the crystal orientation, and (3) Adjustment of the Scherzer focus condition. Related term high-resolution electron microscopy HREM phase contrast Sherzer focus zone axis lattice image 18. crystal growth keyword “ crystal growth” "Crystal growth" means that a single crystal or a polycrystal grows from a crystalline substance through various processes such as solidification from melt, solidification from vapor, and precipitation from solvent. Related term single crystal polycrystal 19. space lattice keyword “ space lattice ” "Space lattice" means a periodic array of a unit lattice (a parallelepiped) in a space. The space lattice is classified into 7 crystal systems according to lattice parameters (a, b, c, α, β, γ). Unit lattices of several crystal systems can locate within them. According to the location of the lattice points, face-centered lattice, body-centered lattice and base-centered lattice are created. As a result, it amounts to 14 type lattices, which are termed Bravais lattices. Lattices other than primitive lattice cause forbidden reflections to occur. Related term unit cell lattice parameter (constant) forbidden reflection extinction rule 20. atomic plane keyword “ atomic plane ” A crystal is regarded as a stacking of atomic planes, which is created by a regular array of atoms. In a (perfect) crystal, different kinds of atomic planes stack periodically. Related term lattice plane stacking fault 21. lattice defect keyword “ lattice defect “ Disorder of the atomic arrangement in a crystal. In a perfect crystal, constituent atoms create a regular and an ordered arrangement. However in a real crystal, the order of arrangement is violated and structural disorder exists. "Lattice defect" is classified into planar faults, line defects and point defects, in terms of its form. Related term stacking fault dislocation point defect 22. lattice parameter (constant) keyword “ lattice parameter (constant) “ The lattice parameters are the quantities specifying a unit cell or the unit of the periodicity of the atomic arrangement. The lattice parameters (constants) are composed of "a, b, c," lengths of the unit cell in three dimensions, and "α, β, γ," their mutual angles. Related term unit cell crystal structure 23. lattice plane keyword “ lattice plane” In a crystal, equivalent atomic planes are aligned in parallel with an equal distance. Thus, a crystal is regarded as an assembly of planes created by atoms. In this context, a set of parallel planes is named a "(crystal) lattice plane." The distance between the neighboring planes is termed the spacing of the plane. In a crystal, there are many lattice planes with different orientations. Related term atomic plane 24. solid solution keyword “ solid solution ” When two or more kinds of substances are mixed and have a uniform structure (particularly in the case of ion crystals and semiconductors), the mixed crystal is called a solid solution. Different atoms are randomly arranged on equivalent lattice sites in the solid solution. Below a certain temperature, the different atoms can take an ordered arrangement. 25. GP zone keyword “ GP zone ” "GP zone" means a plate that is composed of solute atoms segregated on a plane. The zone was discovered independently by A. Guinier and G. D. Preston through the analysis of streaks extending from X-ray Laue spots. It is named Guinier-Preston (GP) Zone after the two researchers. In the case of an age-hardened alloy that consists of Al or Mg but includes minute solute atoms (Cu, etc.), when its super-saturated solid solution is rapidly cooled and undergoes an aging treatment at a low temperature, solute atoms (Cu, etc.) are precipitated as one or two atomic planes with lattice matching on the {001} plane of the parent phase. It is noted that they do not appear as precipitates in the equilibrium state. The GP zone causes age hardening of alloys containing Al or Mg. In a bright-field image, the GP zone shows a line contrast due to lattice distortions. In a high-resolution image, the arrangement of solute atoms is directly observed. 26. magnetic domain keyword “ magnetic domain ” A "magnetic domain" means a region where the directions of all the magnetizations of respective atoms are the same. Related term ferromagnetic material 27-1.antiferromagnetic material keyword “ magnetic material” An "antiferromagnetic material" consists of atoms having magnetic moments but the neighbouring magnetic moments are aligned anti-parallel to each other, thus the net magnetic moment of the material is 0 (zero). The material is magnetized in the direction of a magnetic field like a paramagnetic material when placed in a weak magnetic field. When the magnetic field is increased, it is strongly magnetized in the direction of the magnetic field like a ferromagnetic material. It exhibits a double-hysteresis loop against changes of the magnetic field. Related term ferromagnetic material paramagnetic material diamagnetic material 27-2. diamagnetic material A material that is magnetized in the reverse direction against a magnetic-field direction when placed in the magnetic field, and demagnetized when the magnetic field is removed. Related term ferromagnetic material paramagnetic material antiferromagnetic material 27-3. ferromagnetic material A material that consists of atoms having magnetic moments, which align parallel to each other, thus exhibits strong spontaneous magnetic polarizations without any external magnetic field. In a magnetic domain, all the magnetic moments take the same direction. When an external magnetic field is applied to a ferromagnetic material, strong magnetic moments appear in the direction of the magnetic field, and residual magnetic moments exist even after the magnetic field is removed, thus exhibiting a hysteresis loop of the magnetic moment against the magnetic field. Certain materials show ferromagnetism below a phase transformation temperature, called the Curie temperature Tc, and are paramagnetic (disordering of the moments) above the temperature. Related term paramagnetic material diamagnetic material antiferromagnetic material magnetic domain 27-4. magnetic material A material that is magnetized when placed in a magnetic field. "Magnetic materials" are classified into ferromagnetic material, paramagnetic material, diamagnetic material and antiferromagnetic material, from the viewpoint of how the material is magnetized. Related term ferromagnetic material paramagnetic material diamagnetic material antiferromagnetic material 27-5. paramagnetic material A material that is magnetized in the direction of a magnetic field when placed in the magnetic field, and demagnetized when the magnetic field is removed. Related term ferromagnetic material diamagnetic material antiferromagnetic material 28. real space keyword “real space ” The space in which we exist. In a TEM, the "real space" includes the space of an object to be observed and the space where an image of the object is formed (image space). Related term reciprocal space 29. real lattice keyword “real lattice ” "Real lattice" is a set of points which have an infinitely regular arrangement in the real space and are arranged to be equivalent when viewed from every point. When a structure unit is given to each lattice point, a crystal is formed. Related term reciprocal lattice 30. quasicrystal keyword “quasicrystal ” "Quasicrystal" takes a new ordered structure which has no periodicity but a long-range order with bond orientational order between the constituent atoms. Thus, the quasicrystal is totally different from amorphous. Quasicrystals have been found in many alloys composed of aluminum and two transition metals exhibiting ferromagnetic properties.

HAADF-STEM image of an Al-Mn-Pd two-dimensional quasicrystal taken with a JEM-ARM200F at an accelerating voltage of 200 kV.

In the image, decagonal (D) structure units, star-shaped pentagonal (P) units and hexagonal (H) units are clearly seen. All the D units are joined by edge-sharing linkage, and the gaps between those D units are completely filled with P units and H units. (cf. JEOL News Vol. 50, p25 (2015))

Courtesy of the image: Professor Emeritus K. Hiraga, Tohoku University

31. zone axis keyword “ zone axis ” In a crystal, a group of planes parallel to a certain direction is called a crystal zone, and this direction is termed a "(crystal) zone axis." 32. paraelectric material keyword “ paraelectric material ” "Paraelectric material" generates dielectric polarizations when an electric field is applied to the material and the material looses the polarizations when the electric field is removed. In "paraelectric materials," three kinds of polarizations exist: (1) electronic polarization, (2) ionic polarization, and (3) orientational polarization. In electronic polarization, electrons are displaced against the atomic nucleus. In ionic polarization, positive ions are displaced against negative ions. In orientational polarization, molecules having permanent dipole moments change their directions under an electric field. The paraelectric material has a small permittivity and a small dielectric loss. A material which is called quantum paraelectrics does not transform to a ferroelectric phase but remains at the paraelectric state even around absolute zero temperature due to zero-point oscillation of phonons. Related term ferromagnetic material antiferroelectric material 33. precipitate keyword “ precipitate ” "Precipitate" is a solid formed as a new stable phase separated from the matrix crystal by atoms excessively dissolved in a supersaturated solid solution. When the degree of supersaturation of the dissolved atoms is low, they do not form a phase but are collected on grain boundaries or dislocations. 34. stacking fault keyword “ stacking fault ” A kind of planar lattice defect (planar fault). When considering a perfect crystal to be produced by periodic stacking of (different kinds of) atomic planes, "stacking fault" means a fault where the order is violated. boundary lattice defect atomic plane 35. twins keyword “ twins ” When two adjacent crystals are symmetric with each other about a specific plane or a specific axis, these two crystals are called "twins." 36. phase transformation keyword “phase transformation ” A phenomenon where a substance transforms to a different state by a change of the external conditions (temperature, pressure, magnetic field, etc.). "Phase transformation" is classified into the first-order and the second-order phase transformations. The former exhibits a discontinuity in the first derivative of the free energy with respect to temperature, which includes melting of solids and vaporization of liquids. The latter exhibits a discontinuity in the second derivative of the free energy temperature, which includes the transformation of the ferromagnetic state (iron, etc.) to the paramagnetic state at Curie temperature and the transformation of the alloys from a chemical order state to a disorder state (and vice versa). Related term chemical order/disorder 37. residence time keyword “residence time” "Residence time" is a time when a particular compound or element spends in a system, or a time when a reactant spends in a process vessel or contacts a catalyst. 38．Polycrystal keyword “ polycrystal ” A crystal composed of crystalline particles with different crystal orientations. Related term single crystal 39-1. single crystal keyword “ single crystal ” The single crystal is a crystal in which the constituent unit cells are aligned in the same orientation. A large single crystal is obtained under a specific growth condition. Related term polycrystal 39-2. lanthanum hexaboride single-crystal tip A tip used as a thermoelectron source. A lanthanum hexaboride (LaB6) single crystal, which is sharpened to a cone shape, is used. The LaB6 tip is indirectly heated at about 1800 K. Its brightness is 5×106 A/cm2.sr at 200 kV. The size of the crossover is ～10 μm. The energy spread of the emitted electrons from the filament is ～2 eV. Related term hairpin filament field-emission electron gun FEG 40. unit cell keyword “unit cell” The minimum unit of the periodicity of a crystal. The size and form of the unit cell is defined by six lattice parameters or constants (a, b, c, α, β, γ). Related term crystal structure lattice parameter (constant) 41. short-range order parameter keyword “ short-range order parameter” In the case of a binary alloy, "short-range order parameter" means a probability of existence of atom B around atom A. It can be measured from the intensity of diffuse scattering that appears around a reflection specific to the ordered phase. Related term long-range order parameter ordered and disordered structure 42-1. Substitution keyword “ substitution” "Substitution" means that an atom or a group of atoms in a crystal or a molecule is substituted with other atom or other group of atoms. 42-2. substitutional atom When the other kind of atom (solute atom) occupies an atom position instead of an original atom, the solute atom is termed a "substitutional atom." 42-3. freeze substitution Freeze substitution is a technique to replace amorphous ice with an organic solvent (acetone, etc.) (dehydration) in a biological specimen fixed by rapid freeze fixation, where the specimen is subject to rapid freeze fixation (high pressure freezing or metal mirror freezing (slam freezing)). To prevent destruction of fine structures of the specimen, the substitution is carried out by raising temperature step-by-step from -80 ℃ to 4 °C over a few days. In the course of the substitution, chemical fixation and electron staining are often performed by adding osmium tetroxide and/or uranium acetate. Then, the substituted specimen is returned to room temperature and is subject to resin embedding. A TEM specimen is made by ultrathin sectioning the specimen. Related term rapid freeze fixation metal mirror freezing (slam freezing) high pressure freezing amorphous ice 43. centro-symmetry keyword “ centro-symmtry ” "Centro-symmetry" means that a crystal is symmetric with respect to a certain point. 44. long-range order parameter Keyword “ long-range order parameter ” In the case of binary alloys, a degree of order of atom species A and B increases with decreasing temperature after a substance undergoes a transition from a disordered phase to an ordered phase. The "long-range order parameter" means this degree of order. It can be measured from the intensity change of a specific reflection that appears in an ordered phase. Related term short-range order parameter ordered and disordered structure 45. superlattice keyword “ superlattice “ "Superlattice" is formed, for example, when a structural modulation occurs on a crystal structure to have a longer period (normally an integral multiple of the original period) than that of the original crystal structure. Such a modulation can be formed in a low-temperature phase due to phase transformation. An artificial superlattice is produced as a long-period multi-layer structure which is composed of more than two kinds of layer crystals deposited by molecular beam epitaxy (MBE). The superlattice structures are used for quantum-well laser diodes, high-temperature superconductive materials, and magnetic materials. 46. long period structure keyword “ long period structure” For example, in the phase of CuAuⅠ, five ordered lattices are aligned in a direction followed by another five ordered lattices with an anti-phase shift to the former lattices, resulting into formation of a structure with a unit of 10 times larger than the original lattice. Such a structure is called a "long period structure." The phase CuAuⅠ appears in a narrow temperature range between the ordered phase and the disordered phase. In a diffraction pattern, the reflections from the ordered phase split to diffraction spots appearing at the positions corresponding to a period of 10 times that of the ordered phase. Long period structures appear in intermetallic compounds and SiC. Related term ordered and disordered structure anti-phase boundary 47-1. dislocation keyword “ dislocation ” "Dislocation" is a kind of lattice defect. When a certain region in a crystal undergoes a slip (a displacement), a boundary between the slipped region and the non-slipped region is called a dislocation or a dislocation line. Dislocation includes screw dislocation and edge dislocation. In the case of the screw dislocation, when a round circuit is taken along the crystal lattice (Burgers circuit) around the dislocation (line), the end of the circuit after one round does not get back to the original lattice point but comes to the next lattice point in the direction of the dislocation line. This displacement is termed the Burgers vector which characterizes the dislocation. In edge dislocation, one extra lattice plane (extra half plane) is introduced in the half way of a crystal. The edge line of the extra half plane is the edge dislocation or edge dislocation line. The Burgers vector of the edge dislocation is perpendicular to the dislocation line. Plasticity of a crystal is explained by dislocation motion and multiplication of dislocations. Related term lattice defect weak-beam method partial dislocation stacking fault 47-2. dislocation loop When oversaturated point defects (vacancies or interstitials) accumulate in a plate form, a closed dislocation is produced at the edge of the plate. The closed dislocation is called "dislocation loop." In the case of the vacancy plate, when the atomic planes neighboring to the vacancy plate collapse to retrieve the inherent atomic distance, a stacking fault is produced. Whether the dislocation loop is the vacancy type or the interstitial type is determined by examining whether the dislocation image is formed inside or outside of the dislocation for the diffraction conditions of the positive and negative deviations from the Bragg condition. 47-3. imperfect dislocation partial dislocation 47-4. partial dislocation The magnitude of Burgers vector b of a (perfect) dislocation is defined as the distance from a lattice point to the nearest lattice point. There may exist a meta-stable position for an atom given by a vector ｂ1 whose magnitude is smaller than b. The Burgers vector of the perfect dislocation can split to b = ｂ1+ｂ2. The defects having vectors ｂ1 and ｂ2 are called "partial dislocation." Since the dislocation energy is proportional to the square of the Burgers vector, the splitting (extension) of the perfect dislocation is possible. However, a stacking fault is introduced between two partial dislocations. The energy of the stacking fault determines whether or not the extended dislocation occurs and the width of the stacking fault. When the splitting distance of the two partials is short, the use of the weak-beam method is effective for determining this splitting. Related term dislocation stacking fault 48. crystallographic point group keyword “ crystallographic point group” In crystal symmetry, all the combinations of symmetries that exist with respect to a fixed point in a crystal are called "crystallographic point groups." Symmetry elements consist of rotation(1-, 2-, 3-, 4- and 6-fold), rotary inversion(4-), mirror(m) and inversion(i). 32 independent point groups are constructed by the combinations of the 8 symmetry elements. Related term rotation axis rotary-inversion axis mirror plane inversion center crystallographic space group convergent-beam electron diffraction CBED 49. point defect keyword “point defect ” "Point defect" is defined as atomic-size defect. In particular, when no atom exists at a lattice point, this defect is called "vacancy type point defect." On the other hand, when an atom is introduced into a position other than a lattice point, the defect is termed "interstitial type point defect." Vacancies can exist in a crystal at the thermal equilibrium state and play an important role for diffusion of atoms. Interstitial atoms are normally impurity atoms, but they can be the same atoms of the crystal when the atoms at the lattice points are ejected by irradiating the crystal with high-energy particles. In the latter case, since the interstitial atoms are easy to move, the atoms are likely to disappear by recombination with vacancies. 50-1. Isotropy keyword “ isotropy ” "Isotropy" means that physical properties of a crystalline substance do not change regardless of its crystal orientations. anisotropy 50-2. anisotropy "Anisotropy" means that physical properties of a crystalline substance are different depending on its crystal orientations. isotropy 51. Neel wall keyword “ Neel wall ” "Neel wall" is one type of the boundary structure of magnetic domains whose magnetization directions are antiparallel or different by 180°to each other. This wall is formed in a thin-film specimen. The magnetic dipoles parallel to the specimen surface continuously rotate in planes parallel to the surface at the magnetic wall, and connect to those of the adjacent domain with the opposite magnetization. In a diffraction pattern formed by two adjacent magnetic domains containing a Neel wall, a diffuse intensity arc appears connecting the diffraction spots from the two domains. Related term Bloch wall Lorentz electron microscopy 52. inversion center keyword “ inversion center ” A symmetry element of the crystallographic point group. An operation that transforms a coordinate (x, y, z) into (-x, -y, -z) (that is, the signs of the coordinates of each point are changed) is called the inversion operation. When this symmetry is operated for a crystal, the crystal can be equivalent to that before the operation. In this case, the point leaving fixed by the operation is called "inversion center." Related term crystallographic point group rotation axis rotary-inversion axis mirror plane 53. inversion domain boundary keyword “ inversion domain boundary” "Inversion domain boundary" separates two adjacent crystals which coincide with each other by an inversion operation. Related term boundary 54-1. amorphous keyword “ amorphous ” A solid substance in which the arrangement of atoms and/or molecules is irregular and disordered. 54-2. amorphous ice Amorphous ice means ice that does not take a crystalline state. When water is cooled below the melting point, ice crystal is formed and grows until its temperature reaches the re-crystallization temperature. Since formation of ice crystals can cause destruction of fine structures of a biological specimen, amorphous-ice formation without formation of ice crystals is required when rapid freeze fixation is applied. Thus, ice-crystal formation should be suppressed by cooling the specimen as rapid as possible down to the re-crystallization temperature. Related term rapid freeze fixation high pressure freezing freeze substitution metal mirror freezing (slam freezing) cryo-electron microscopy ice embedding 55. composite crystal keyword “ composite crystal ” A "composite crystal" is composed of two or more crystals whose structures have incommensurate periods (not expressed by an integral ratio) to each other. Related term incommensurate structure 56-1. Impurity keyword “impurity ” "Impurities" are defined as substances contained in a pure substance. When a trace amount of impurities are doped into a semiconductor, energy levels characteristic of impurities are created in the band gap, from which electrons are excited to the conduction band or to which electrons are accepted from the valence band. 56-2. impurity atom Foreign atoms mixed in a crystal, which are different kind from constituent atoms of the crystal. An "impurity atom" causes point defect, which is one of lattice defect. Related term point defect 56-3．impurity level "Impurity level" is defined as an energy level created in the band gap in a semiconductor, which is introduced by impurity atoms. Related term cathodoluminescence 57． incommensurate structure keyword “ incommensurate structure” "Incommensurate structure" is defined as a structure where the periodicity of a structure arising from phase transformation cannot be expressed by a simple integral ratio with respect to the periodicity of the basic structure before phase transformation. Related term superlattice phase transformation 58. Bloch wall keyword “bloch wall” "Bloch wall" is one type of the boundary structure of magnetic domains whose magnetization directions are antiparallel or are different by 180°to each other. The magnetic dipoles continuously rotate in planes parallel to the magnetic boundary and finally connect to those at the adjacent magnetic domain with opposite magnetization. This structure is formed in a bulk specimen with a thickness of more than 100 nm. The thickness of the Bloch wall is about 50 nm for iron. In a diffraction pattern formed by two adjacent magnetic domains containing a Bloch wall, a diffuse intensity line appears connecting the diffraction spots from the two domains. Related term Neel wall Lorentz electron microscopy 59. ferroelectric domain keyword “ ferroelectric domain ” The ferroelectric material has spontaneous electric polarizations under no external electric field. A "ferroelectric domain" means a region where the directions of all the polarizations are the same. Related term ferromagnetic material 60. displacement keyword “ displacement ” In crystallography, "displacement" means atomic displacement of an atom from a lattice point due to dislocation or stacking fault, and atomic displacement of an atom arising from (crystal) structural change at phase transformation. 61. deformation keyword “ deformation ” "Deformation" means changes in shape or size of a substance due to contraction or expansion arising from changes of stress, temperature or chemical condition. 62. segregation keyword “ segregation ” A phenomenon where the impurities or constituent elements in a metal or an alloy become unevenly distributed. "Segregation" often occurs when coagulation of alloy occurs. 63. modulated crystal keyword “ modulated crystal ” A "modulated crystal" takes an additional modulation wave of atomic displacement or composition to the fundamental structure, whose wavelength is a non-integral number of the period of the fundamental structure. The modulation provides satellite reflections around the fundamental reflections. The features of the satellite reflections are different depending on the modulation to be a transverse wave type or a longitudinal wave type. Related term incommensurate structure superlattice phase transformation 64. Miller index keyword “ Miller index ” "Miller index (h, k, l)" specifies the lattice plane of a crystal, which is given by a/u, b/v, c/w, where u, v and w are the intercepts of the lattice plane on the crystal axes or coordinates at which the lattice plane intersects the crystal axes, and a, b and c are the unit cell dimensions of the crystal. If any of the ratios (a/u, b/v, c/w) take fractional number, the elements of the Miller index or the ratios are rewritten by integral number. Related term lattice plane 65. dielectric material keyword “ dielectric material ” "Dielectric material" is equivalent to "insulator." In a dielectric material, no free electrons exist or all electrons are bound to atoms or molecules. When an electric field is applied to a dielectric material, no electric current flows because of no free electrons in the material, but positive and negative charges are created on one surface and the other surface due to dielectric polarization, electric energy being stored. Related term ferromagnetic material paraelectric material antiferroelectric material metal 66. dielectric constant keyword “ dielectric constant ” A quantity to express the degree of polarizability of a material when a voltage is applied to. Or a quantity to express the amount of electrical energy to be stored in a material. 67. screw axis keyword “ screw axis ” A symmetry element of the crystallographic space group. When the whole crystal is rotated by a certain angle(180°, 120°, 90°, 60°) with respect to an axis and successively translated along the axis by a length of 1/2, 1/3, 1/4 or 1/6 of the crystal unit-cell, the translated crystal can be equivalent to the original crystal. In this case, this axis is called "screw axis." The screw axes are denoted by 21,31,32,41,42,43,61,62,63,64,65. Related term crystallographic space group glide plane 68. grain boundary keyword “ grain boundary ” "Grain boundary" separates respective crystalline particles with different orientations in a polycrystalline solid. Grain boundaries are also called crystalline grain boundaries.

High-resolution HAADF-STEM image of polycrystalline silicon taken at an accelerating voltage of 300 kV. The boundary indicated by red allows is a grain boundary of crystalline silicon. The image reveals that the dumbbells of silicon atoms change their orientations across the boundary. This grain boundary is expressed by Σ3, [110]/{111}. Related term boundary